empirical formula - the simplest formula we can write.  Many compounds may have the same empirical formula

 

            carbohydrates:  CH2O

 

molecular formula - tells us exactly how many atoms of each element are in a single molecule of that compound.  Again, many compounds may have the same molecular formula. 

 

            ribose:  C5H10O5

            glucose & fructose:  C6H10O6    - need structural formulas to tell difference

 

molecular compounds –consist of only nonmetals:

            naming binary molecular compounds:    

            CO, CO2, NO, NO2, N2O3, N2O4

                        give number as bi, tri etc.  last element (one furthest to right on table) ends                     in –ide)

 

                        These are molecular compounds – composed only of nonmetals

 

                        Table 2.3

 

Ionic compounds – composed of a metal and a nonmetal – may be simple and have only two elements such as salt, NaCl = sodium chloride

 

or complex with a poly atomic ion such as sodium phosphate Na3PO4 where PO­4 is a single ion.

 

Monoatomic ions – from periodic table, the charge on many ions can be predicted.

            figure 2-10      

            metals = positive

            nonmetals = negative

            negative charged ion always listed last

 

            do some examples

 

Polyatomic ions – composed of nonmetals that together carry a charge

            Table 2-4

 

When ionic compounds are formed, the charges must sum up to zero. 

 

Since these compounds involve charges, they are also considered polar.  Because of this, water loves to hang around and often sticks very tightly to the solid compounds to form hydrates.  In the formula of a hydrate, we indicate the number of waters associated with each ionic unit.

 

            copper (II) chloride heptahydrate = CuCl2 . 7 H2O

 

Acids and bases:

            mineral acids and bases are made from ionic compounds that, according to        Arrhenius, produce H+ or OH- when dissolved in water.

 

            When dissolved in water, ionic compounds break apart into their component     anions and cations.  Therefore when an anion has its charge balanced by       hydrogens, it is an acid:

 

            nitrate ion:  NO3- forms HNO3 = nitric acid

            nitrite ion:   NO2- forms HNO2 = nitrous acid

           

            what do you notice about naming conventions?

 

            chlorite ion:  ClO2- forms HClO2 = chlorous acid

            phosphate ion:  PO3-3 forms H3PO4 = phosphoric acid

 

            Table 2.5  exchange a different halogen in for chlorine to show how names         change.

 

Any ionic compound containing hydroxide ion (OH-) will be a base and is named as per any other ionic compound – sodium hydroxide, etc.